It is given that,
$\text{Range} = \text{Maximum Score} - \text{Minimum Score} \le 25$
Let the student scores arranged in descending order be: $s_1 \ge s_2 \ge s_3 \ge s_4 \ge \dots$
From (S1): The highest score is $100 \implies s_1 = 100$.
From (S2): The fourth highest score is $76 \implies s_4 = 76$
Because the scores are ordered, the second and third highest scores ($s_2$ and $s_3$) must fall between $s_4$ and $s_1$: $76 \le s_4 \le s_3 \le s_2 \le s_1 = 100$
$\text{Max Difference} = s_1 - s_4 = 100 - 76 = 24$
Since $24 \le 25$, the scores of these four students ($s_1, s_2, s_3, s_4$) are guaranteed to be within $25$ of each other.
So answer is Option A